Abstract
This study investigates newly developed sand/gravel-sized mayenite composite pellets with cellulose-based binders as a chloride (Cl−) remover that is compatible with saline groundwater also impacted by hydrocarbons. The mayenite pellets remove Cl− from impacted oilfield groundwater with 60–90 % efficiency in the range of salinity values found at field sites (< 20,000 mg/L total dissolved solids, TDS) in the presence of hydrocarbons, without agitation. The pellet reactions are driven by hydration, anion exchange, adsorption, and mineral phase reconstruction with increasing intraparticle diffusion and pellet heterogeneity during Cl− removal. Cl− removal is significantly correlated with changes in the quantities of pellet components. Mayenite is a key mineral for Cl− removal, during which hydrocalumite is formed. However, high mayenite purity is not required due to the contributions of non-mayenite pellet components (CaO and Al2O3) to Cl− removal. Drastic morphological transformations of pellet minerals occurred from honeycomb-like to cubic or hexagonal structures. Sand/gravel-sized pellets had a comparable Langmuir qmax of 74.5 mg/g. Mayenite pellets are not affected by hydrocarbons in both aqueous and nonaqueous phases. The removal of hydrocarbons observed was likely associated with porous pellet structures. TDS and competitive anions in impacted groundwater regulate the mayenite pellet reactions for Cl− removal.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
