Abstract

In addition to studies of reaction kinetics by a transient method in a batch reactor (nonsteady-state), such studies should also be carried out by continuous operation in a stirred-flow reactor (steady-state). Only in this way, for instance, can the extent be recognized to which the simplifying assumptions often made in the evaluation of industrial kinetics from transient investigation are reasonable and whether the kinetics obtained are applicable to complex reactor design. The thermokinetic reactor (TKR), with which it has only been possible to measure the rate of heat evolution in experiments under transient conditions (batch TKR), has now been modified so that investigations can also be carried out in the stirred-flow manner (steady-state TKR).

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