Development And Characterization Of Biodiesel From Non-Edible Vegetable Oils Of Indian Origin

Abstract

Increased environmental awareness and depletion of fossil fuel resources are driving industry to develop alternative fuels that are environmentally more acceptable. Vegetable oils are potential alternative fuels. Vegetable oils in India are produced from numerous oilseed crops. While all vegetable oils have high energy content, most require some processing to ensure safe usage in internal combustion engines. Most detrimental properties of oils are its high viscosity, low volatility and polyunsaturated character. The most widely used method is to convert vegetable oils into biodiesel. Biodiesel fuels are primary esters, which are produced by transesterifcation of vegetable oils. Several vegetable oil esters have been investigated so far in different parts of the world and found suitable to be used in diesel engines. In present investigation, methyl esters of some non-edible vegetable oils of Indian origin (castor, linseed and ricebran) are prepared and their properties have been evaluated. The effect of temperature on the viscosity of vegetable oils and their esters was studied. Viscosity of vegetable oils drastically decreases after transesterification. Flash point and specific gravity of neat ricebran and linseed oil and their esters were also evaluated in this investigation. Introduction Increased environmental concerns, tougher clean air standards, increasing prices and uncertainties concerning petroleum availability necessitate the search for a viable alternative fuel, which is more environment friendly, hence vegetable fuel studies have become prominent among various potential alternatives. The idea of using vegetable oils as fuel for diesel engine is not new. When Rudolf diesel first invented t he diesel engine, he demonstrated it at the 1900 world exhibition in Paris, employing peanut oil and said “The use of vegetable oils for engine fuels may seem insignificant today, but such oils may become in course of time as important as petroleum and the coal tar products of the present time” [1]. In the 1930’s and 1940’s, vegetable oils were used as diesel fuels from time to time, but usually only in emergency situations. Recently, because of increase in crude oil prices, limited resources of fossil fuels and environmental concerns, there has been a renewed focus on vegetable oils and animal fats to make biodiesel fuels. Biodiesel is biodegradable, non-toxic and essentially free from sulphur. It is renewable and can be produced from agriculture & plant resources. While short-term tests are positive, long-term usage of neat vegetable oils or their blends with diesel leads to various engine problems such as injector coking, ring sticking, injector deposits etc. [2,3]. High viscosity, low volatility and a tendency to polymerize within the cylinder are the root cause of many problems associated with direct usage of these oils as fuels [2]. The process of transesterification yields vegetable oil esters, which have shown promise as alternative diesel fuel as a result of improved viscosity & volatility characteristics. Several researchers investigate the different vegetable oil esters [3-7] and found esters comparable to diesel fuel. Muniyappa et. al., optimized the transesterification process for Soyabean oil, [3] . Freedman et. al. investigated the effect of various parameters on vegetable oil yield [4]. Several researchers transesterified the vegetable oils and found that properties are quite comparable to mineral diesel and performance and emission characteristics of CI engines using biodiesel in different proportion as a blend with mineral diesel improves [5-10]. Agarwal et.al. developed linseed oil methyl esters and found it comparable to diesel with improved emission characteristics compared to diesel [5,6]. Physical wear of various vital parts, injector coking, carbon deposits etc. were found to be substantially lower in case of 20% biodiesel fuelled engines [11]. The objective of this study is to investigate the effect of transesterifcation on the viscosity and other properties of non-edible vegetable oils of Indian origin and to evaluate the effect of temperature on the viscosity of neat vegetable oil and their methyl esters. Detailed results on the viscosity and other properties of oils and their esters are presented in this paper. Composition of Vegetable Oils Petroleum diesel fuel is a complex mixture of hydrocarbons with carbon atoms ranging between 12-18, whereas vegetable oils are mixture of organic compounds ranging from simple straight chain compound to complex structure of proteins and fat-soluble vitamins and are commonly referred as triglycerides. Vegetable oils are usually triglycerides, generally with number of branched chains of different length, and have structural notation as shown.