Developing a model for chloride transport through concrete considering the key factors

Abstract

The corrosion of chloride-induced on concrete is affected by many factors. In this research, an innovative empirical model was developed to predict the long-term chloride migration behavior in concrete, considering the effects of water-cement ratio, time, bonding effect, temperature, relative humidity, and concrete deterioration. The reliability and validity of the results evaluated by the empirical prediction model were verified by the chloride concentration data in concrete specimens exposed to the marine environment for 3, 5, and 10 years reported in the literature. Combined with the established empirical prediction model, the concrete model was regarded as a three-phase composite material composed of mortar, coarse aggregate, and interfacial transition zone. The effects of key factors on chloride migration were further analyzed by using the mesoscopic finite element numerical simulation method. It was observed that when temperature increases from 5 ℃ to 65 ℃, chloride diffusion depth rises by 3.3 times. When relative humidity increases from 20% to 100%, chloride diffusion depth rises by 4.3 times. Also, the water-cement ratio, concrete deterioration, and chloride binding effect have a non-negligible impact on chloride migration.