Abstract
Using the inversion-recovery method, deuterium longitudinal relaxation times, ( T 1), of [ 2H 4]methanol and [ 2H 3]acetonitrile in enriched methanol—water and acetonitrile—water mobile phases were measured for the neat binary mixtures, and for the mixtures in contact with two different monomeric C 18 reversed-phase stationary phases. Changes in the deuterium relaxation times for the organic modifiers in contact with the stationary phase compared to those observed in neat solution give a qualitative understanding of the degree of association of the organic components with the stationary phase. Both bulk solution microstructure and stationary phase C 18 bonding density play important roles in determining bonded phase solvation.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
