Abstract
Using the inversion/recovery method, deuterium ( 2 H) longitudinal relaxation times, (T 1 ), of deuterium oxide were measured for binary solutions of methanol and D 2 O and acetonitrile and D 2 O and for these mixtures in contact with two different reversed-phase liquid chromatographic stationary phases. Changes in the D 2 O T 1 for the solutions in contact with the stationary phase compared to those observed for the solutions alone give a qualitative understanding of the degree of association of water with the stationary phase
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