Abstract
A reversed-phase HPLC method has been developed for the determination of vinylmagnesium chloride and vinylmagnesium bromide, based on the assay of 1-(9-anthryl)propen-2-ol, the product in the reaction between a vinylmagnesium halide and 9-anthraldehyde. The HPLC system with UV detection and an acetonitrile–water mobile phase containing phosphoric acid buffer was used for the separation and quantification of the reaction product after extraction. The method is selective for 1-(9-anthryl)propen-2-ol and linear response was established at 227 nm in the 0.002 to 0.5 mg ml–1 concentration range. Vinylmagnesium halide concentration was calculated by using benzophenone as an external reference standard to standardize the response of authentic 1-(9-anthryl)propen-2-ol.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
