Abstract
A method for determination of the vibrational distributions and populations of individual vibrational levels of vibrationally-nonequilibrated carbon dioxide in bend-stretch manifold and asymmetric stretching mode was developed and substantiated. The method is based on the measurements of integrated radiation intensity in the wide spectral intervals of the 15 μm CO 2 band and total emissivities of its appropriate Q-branches. Computations of radiation intensities and emissivities in P and R-branches were performed by using vibrational-rotational band models and in Q-branches by the direct “line-by-line” integration. It was shown that vibrational temperature of CO 2 asymmetric stretching mode may be determined from the measurements of integrated radiation intensity of the 15 μm band. The populations of individual levels of the bend-stretch manifold may be obtained from the measurements of total emissivities of some Q-branches of the 15 μm band. The procedure of the CO 2 lower vibrational levels populations determination under the conditions typical of 18 μm and 9–11 μm CO 2 laser cavities is described.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
