Abstract

Uranium in phosphate rock can be determined radiometrically using gamma-counting and spectrophotometrically using arsenazo I. In the latter case the rock is dissolved in HNO3, then uranium is extracted with tributyl phosphate, stripped with hot water and determined. For the determination of uranium in technical phosphoric acid, the fluorosilicate ion present as impurity must first be precipitated, the uranium separated on Amberlite IRA-400 in the sulfate form, then determined in the eluate spectrophotometrically by arsenazo I. Radium can be determined in leach solutions by the emanation method.

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