Abstract

AbstractThe phase diagram of blends of liquid crystalline polymer (LCP) and polycarbonate (PC) was constructed. The effect of temperature on morphological development in melt‐blended samples was examined with a polarized light microscope, in conjunction with a heating stage. Phase separation in the blend was observed as the temperature was increased. For a particular LCP/PC blend composition, two‐phase separation temperatures (Tsp1 and Tsp2) were determined. Consequently, the corresponding phase diagram relating to phase separation was constructed. It was divided into three regions. No phase separation occurred when the blend was below Tsp1. However, a slight phase separation was detected when the temperature was between Tsp1 and Tsp2. Moreover, pronounced phase separation was observed when the blend was at a temperature above Tsp2. The phase‐separated structure varied according to the initial composition of the blends. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2009

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