Abstract
The propargylsilane, 1,3-bistrimethylsilylbut-1-yne, 11 reacts with aldehydes in the presence of titanium tetrachloride in anti S E2′ reactions, but with a low level of stereospecificity, 75:25 with 2,4-dinitrobenzaldehyde and close to 50:50 with isobutyraldehyde.
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