Abstract

The thermodynamic activities of liquid CuLa alloys were obtained at 1549 K by Knudsen effusion experiments. The experimentally known concentration and temperature dependences of thermodynamic properties of liquid CuLa alloys are explained on the basis of an association model. These results are discussed in comparison with the enthalpy of crystallization and the crystallization temperature as well as the enthalpy of melting and the melting temperature of lanthanum-rich glassy and crystalline alloys respectively.

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