Abstract
Over 70 transitions among the lowest six vibrational states of C35Cl+ and C37Cl+ have been measured between 1070–1210 cm−1. The spectrum has been fitted to a sixth order Dunham expansion to yield an accurate mapping of the Born–Oppenheimer potential function of CCl+. The spectroscopic constants obtained are ωe =1177.7196(8) cm−1, ωexe =6.6475(3) cm−1, and Be =0.797 940(3) cm−1. The rotational constants for both CCl+ isotopes reported here show the results of the previous electronic emission studies to be incorrect. A fit of the data to a Morse function yields a dissociation energy D of 52 828(50) cm−1. The rotational temperature has been determined as 540 K±30%. The increase in the effective vibrational temperature with vibrational excitation indicates that CCl+ is formed with high internal energy.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
