Abstract
A novel method of separating and determining palladium as the chloro complex PdCl 4 2− in the presence of rhodium(III), ruthenium(III), osmium(III) and irridum(III) chloro complexes by capillary zone electrophoresis (CZE) is described. On-column direct UV detection was achieved at 214 nm and the detection limits were lower than 20 ppb. By adding a suitable long-chain cationic surfactants, 0.2 m M cetyltrimethylammonium bromide, to the carrier electrolyte to create a layer of positive charges at the capillary wall and by reversing the polarity of the CZE system (cathodic injection and anodic detection scheme), analyte anions were caused to migrate in the direction of the electroosmotic flow, and thus the analysis time (3.0 min) was shortened. The effect of sample stacking on the plate number was investigated.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
