Determination of chlorine in coal via the SrCl molecule using high-resolution graphite furnace molecular absorption spectrometry and direct solid sample analysis

Abstract

In this study, the determination of chlorine in coal is described via molecular absorption of the strontium mono-chloride (SrCl) molecule at 635.862nm using high-resolution continuum source graphite furnace molecular absorption spectrometry (HR-CS GF MAS) and direct solid sample analysis. The pyrolysis and vaporization temperatures were optimized and the measurements are accomplished with a platform coated with zirconium as a permanent chemical modifier in order to increase the sensitivity of the gaseous SrCl molecule generated in the graphite furnace. The optimum pyrolysis and vaporization temperatures were 700°C and 2100°C, respectively. Under optimized conditions, the limit of detection and characteristic mass of the method were 0.85 and 0.24ng, respectively. The accuracy of the method has been verified using four certified reference materials and one not certified reference material of coal, and the results were in good agreement with the certified or reference values.