Determination of aluminum in botanical samples by adsorptive cathodic stripping voltammetry as Al-8-hydroxyquinoline complex

Abstract

A fast and sensitive new procedure for the determination of total aluminum by adsorptive cathodic stripping voltammetry (AdCSV) in plant samples consumed for dietary and/or medicinal purposes was described. The Al(III)-8-hydroxyquinoline (Al-8HQ) complex was adsorbed on a hanging mercury dropping electrode (HMDE) at 0.300V versus Ag/AgCl electrode during a 30s accumulation time. An electrochemical cell containing 0.024molL−1 ammonia–ammonium acetate buffer (pH6.80) as supporting electrolyte and 7.43mgL−1 8-hydroxyquinoline (8-HQ) as ligand for aluminum were employed. A linear response was observed over the 8.54×10−8 to 2.35×10−7molL−1 range with a limit of detection (LOD) of 8.54×10−8molL−1 and a relative standard deviation (RSD; n=3) of 1.86% for 8.54×10−8molL−1 aluminum solution. Aluminum contents in green tea (Camellia sinensis), carqueja (Baccharis genistelloides), cascara sagrada (Rhamnus purshiana) and senna (Cassia acutifolia) were 502.5±14.1, 195.6±21.0, 309.1±11.7, 205.6±16.1μg aluminum per g of dry tea, respectively. The accuracy of the developed method was evaluated by flame atomic absorption spectrometry (FAAS) and all of the results were similar. It indicates that AdCSV could be efficiently applied in the determination of aluminum as 8-HQ complex in real food samples.