Detergent residues in textiles

Abstract

The purpose of this study was to determine concentrations of detergent residues in textiles washed with three types of detergents. One detergent contained phosphate. In the other two (concentrated or ecological detergents) phosphate had been replaced by zeolite, which contains silicates. The textiles were washed using two programmes for coloured materials (at 60°C). The programmes differed with regard to volume of rinse water and number of rinsings. Detergent residues in textiles were determined chemically. Zeolite particles were determined electron microscopically. The results showed that most of the detergent residues remaining in textile strips were anionic tensides. They increased in proportion to the quantity of detergent used for washing. The least residues were left by concentrated detergents. Anionic tensides are suspected of causing skin irritation, probably allergy in atopic persons. Zeolite particles may irritate skin mechanically or cause through irritation respiratory distress. Washing programmes using less rinse water than other programmes increased detergent residues by 30%. It is concluded that there is a positive linear relationship between concentration of detergent and residues in textiles, and a negative linear relationship between water volume and residues in textiles after laundering. This could be of considerable importance from a health point of view and should be evaluated before any detergent is marketed. A methodology combining different standardized methods for analysing detergent residues in textiles was developed in this study.