Detector and dispersive delay calibration issues in broadband 2D electronic spectroscopy

Abstract

Precision of two-dimensional (2D) electronic spectroscopy can be affected by imprecise calibration of the optical spectrometer and coherence time delay line. This would result in 2D spectral line shapes with twisted phase, where absorptive and dispersive parts of the signal are mixed and unrecoverable. We demonstrate two efficient and easily implementable techniques for precise spectrometer and wedge-based delay line calibration that assure acquisition of correct spectral phase in 2D spectroscopy measurements.