Abstract
Infrared absorption spectra of the SiH free radical have been detected in a silane plasma discharge. In addition to fundamental band transitions some hot band lines have been identified from predictions derived from optical and FTIR data. Low Q-branch transitions in both 2Π1/2 and 2Π3/2 states of the fundamental have been accurately measured and incorporated in a new set of predictions based on the present work and earlier FTIR data.
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