Abstract
Methane (CH4) display spectral features in several regions of the infrared range (0.75–14 µm), which can be used for the remote mapping of emission sources through the detection of CH4 plumes from natural seeps and leaks. Applications of hyperspectral remote sensing techniques for the detection of CH4 in the near and shortwave infrared (NIR-SWIR: 0.75–3 µm) and longwave infrared (LWIR: 7–14 µm) have been demonstrated in the literature with multiple sensors and scenarios. However, the acquisition and processing of hyperspectral data in the midwave infrared (MWIR: 3–5 µm) for this application is rather scarce. Here, a controlled field experiment was used to evaluate the potential for CH4 plume detection in the MWIR based on hyperspectral data acquired with the SEBASS airborne sensor. For comparison purposes, LWIR data were also acquired simultaneously with the same instrument. The experiment included surface and undersurface emission sources (ground stations), with flow rates ranging between 0.6–40 m3/h. The data collected in both ranges were sequentially processed using the same methodology. The CH4 plume was detected, variably, in both datasets. The gas plume was detected in all LWIR images acquired over nine gas leakage stations. In the MWIR range, the plume was detected in only four stations, wherein 18 m3/h was the lowest flux sensed. We demonstrate that the interference of target reflectance, the low contrast between plume and background and a low signal of the CH4 feature in the MWIR at ambient conditions possibly explain the inferior results observed for this range when compared to LWIR. Furthermore, we show that the acquisition time and weather conditions, including specific limits of temperature, humidity, and wind speed, proved critical for plume detection using daytime MWIR hyperspectral data.
Highlights
Methane (CH4) is the main component of natural gas
Assuming the radiative transfer model proposed by Griffin, et al [11], the images acquired at midwave infrared (MWIR) and longwave infrared (LWIR) ranges with the SEBASS sensor over the field experiment of controlled CH4 release were processed using the same methodology for atmospheric compensation, emissivity retrieval, and plume mapping
The results obtained from the airborne data collected in this range proved inferior when compared to those yielded in the LWIR window, since the radiation emitted by CH4 in ambient conditions is very low in the MWIR range
Summary
Methane (CH4) is the main component of natural gas. The detection of CH4 plumes originated either from natural seepages or leakages can assist the oil and gas industry in the discovery of new petroleum plays and environmental monitoring of refineries and pipelines. CH4 has absorption features along the entire infrared spectral range (0.75–14 μm—see Figure S1 in Supplementary Materials). These features result from four main C–H fundamental vibrations, v1, v2, v3, v4, centered at 2.3 μm, 6.5 μm, 3.3 μm, and 7.7 μm, respectively [4]. For the first time, we test the detection limits of data acquired with the SEBASS sensor in the MWIR range for mapping CH4 plumes, based on a controlled release field experiment. The same image processing techniques applied to the MWIR were used to process SEBASS LWIR data acquired for the same experiment [2], intending to evaluate the efficacy in the detection of CH4 plumes in both spectral ranges
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