Detection of H 2S down to ppb levels at room temperature using sensors based on ZnO nanorods

Abstract

ZnO sensors were fabricated from ZnO nanorods prepared by a hydrothermal method and their gas-sensing properties were investigated. It was found that the phase composition of the product and the gas-sensing properties were dependent on the preparation conditions (the presence of surfactant and the ratio of V ZnA c 2 ( 0.50 M ) / V NaOH ( 5.0 M ) ). The sensor prepared at a ratio of V ZnA c 2 ( 0.50 M ) / V NaOH ( 5.0 M ) = 1 without any surfactant exhibited the best performance, which was characterized by high response and good selectivity to low concentrations of H 2S at room temperature. The sensor also had a high response, high selectivity and short response time to low concentrations of C 2H 5OH at 350 °C. These characteristics make the sensor to be a promising candidate for practical materials detecting low concentrations of H 2S and C 2H 5OH. Especially, the response to 0.05 ppm H 2S attained 1.7 at room temperature.