Designed Synthesis of PDI/BiOCl-BiPO4 Composited Material for Boosted Photocatalytic Contaminant Degradation

Abstract

Enhancing the photocatalytic performance for contaminant degradation to accelerate the large-scale application of photocatalysis still is an enduring challenge. Herein, ternary PDI/BiOCl-BiPO4 composited materials with the different contents of PDI were designed and constructed by the multi-step compound method. The tetracycline hydrochloride and rhodamine B were chosen as targeted pollutants to investigate the photocatalytic performance of PDI/BiOCl-BiPO4 composited materials. The structure and component of BiOCl-BiPO4 and PDI/BiOCl-BiPO4 samples were detailedly characterized by a sequence of physical and chemical characterizations. The optimized PDI/BiOCl-BiPO4 sample, namely PDI(5%)/BiOCl-BiPO4, exhibited the excellent photocatalytic activity for tetracycline hydrochloride and rhodamine B degradation. The major active species that were holes (h+) and superoxide radicals (•O2−) also can be determined in the photocatalytic degradation process by active species trapping experiments. Furthermore, the photoelectrochemical and fluorescence measurements manifest the crucial role of PDI material. It can reduce the recombination of photo-excited charge carrier and improve the separation and transfer of photo-generated electron-hole pairs, which is beneficial to the photocatalytic reaction process. It is anticipated that our work would provide a counterpart to prepare the high-efficiency composited material in heterogeneous photocatalysis.