Design, phase equilibria, and coarsening kinetics of a new [formula omitted] precipitation-hardened multi-principal element alloy

Abstract

Multi-principal element alloys (MPEAs), with dispersed nanometric precipitates in a ductile matrix, are attracting a considerable amount of literature’s attention. Understanding the coarsening kinetics and potential properties of such alloys is crucial for future developments in the field. In the present study, we report a new precipitation-hardened multi-principal element alloy, Cr29.7Co29.7Ni35.4Al4.0Ti1.2 (at%), developed with the aid of the CALPHAD method. The alloy has a tough Cr-Co-Ni FCC matrix and nanometric L12 precipitates. After standard heat treatments, the alloy was aged at 850 °C for different aging times and the coarsening kinetics was investigated. The evolution of mechanical properties as a function of aging time was evaluated through microhardness tests. An increment of 106 HV 0.5 was observed compared to the sample in the solution-treated condition. This hardness increment was higher than that of conventional superalloys with a similar volume fraction of precipitates. Experimental data indicate that particle growth during coarsening is governed by diffusion controlling mechanism. The coarsening rate constant was lower than that of traditional wrought superalloys aged at the same temperature, indicating better thermal stability of the current MPEA. Furthermore, experimental particle size distributions show a good correlation with the curve predicted by the Lifshitz–Slyozov–Wagner (LSW) theory. Deviations and the applicability of this theory for MPEAs are discussed.