Abstract

Results of a pilot study with a spectro-streak apparatus applying a grating microspectrometer with a self-focusing reflection grating are reported. The microspectrometer chip (dimensions: 17×6.4 mm2; 125 μm effective thickness of the three-layer x-ray resist system), fabricated with the versatile LIGA technique, has been adapted to a picosecond streak camera. Performance tests have been carried out with a fluorescent probe exhibiting a dynamic Stokes shift of the exciplex fluorescence band due to solvation of the charge transfer dipole within about 400 ps. The use of a LIGA microspectrometer in ultrafast spectroscopy proved to be of advantage in time-resolved studies of complex luminescence spectra where a moderate spectral resolution is required and a large spectral range must be covered.

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