Abstract
The novel aluminium-tin bonded complex, bix(methylcyclopentadienyl)tin-aluminium trichloride has been synthesised from its two components. Its infrared spectrum has been recorded and normal modes assigned by comparison with bis(methylcyclopentadienyl)tin. A structure for the complex is proposed in which the angular “sandwich” nature of the free ligand is preserved. From the infrared spectrum of the bis(methylcyclopentadienyl)lead, it is deduced that this compound isostructural with the analogous tin compound.
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