Abstract

Deposition of Cu particles by electrolysis at constant electrode potential and by internal electrolysis methods was investigated. The composition of deposited material was confirmed by optical and scanning electron microscope methods. Combination of electrolysis at constant electrode potential with internal electrolysis method was found most effective for fabrication of nanoparticle arrays. Single crystalline Cu particles are fabricated by internal electrolysis, while polycrystalline ones obtained by combined chronopotentiometric and internal electrolysis methods. The formation mechanism of Cu nanoparticles is described.

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