Dentin Bond Integrity of Filled and Unfilled Resin Adhesive Enhanced with Silica Nanoparticles-An SEM, EDX, Micro-Raman, FTIR and Micro-Tensile Bond Strength Study.

Aasem M Alhenaki,Tariq Abduljabbar,Esra A Attar,Abdullah Alshahrani,Imran Farooq,Fahim Vohra

doi:10.3390/polym13071093

Aasem M Alhenaki, Tariq Abduljabbar + Show 4 more

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https://doi.org/10.3390/polym13071093

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Abstract

The objective of this study was to synthesize and assess unfilled and filled (silica nanoparticles) dentin adhesive polymer. Methods encompassing scanning electron microscopy (SEM)—namely, energy dispersive X-ray spectroscopy (EDX), micro-tensile bond strength (µTBS) test, Fourier transform infrared (FTIR), and micro-Raman spectroscopy—were utilized to investigate Si particles’ shape and incorporation, dentin bond toughness, degree of conversion (DC), and adhesive–dentin interaction. The Si particles were incorporated in the experimental adhesive (EA) at 0, 5, 10, and 15 wt. % to yield Si-EA-0% (negative control group), Si-EA-5%, Si-EA-10%, and Si-EA-15% groups, respectively. Teeth were set to form bonded samples using adhesives in four groups for µTBS testing, with and without aging. Si particles were spherical shaped and resin tags having standard penetrations were detected on SEM micrographs. The EDX analysis confirmed the occurrence of Si in the adhesive groups (maximum in the Si-EA-15% group). Micro-Raman spectroscopy revealed the presence of characteristic peaks at 638, 802, and 1300 cm−1 for the Si particles. The µTBS test revealed the highest mean values for Si-EA-15% followed by Si-EA-10%. The greatest DC was appreciated for the control group trailed by the Si-EA-5% group. The addition of Si particles of 15 and 10 wt. % in dentin adhesive showed improved bond strength. The addition of 15 wt. % resulted in a bond strength that was superior to all other groups. The Si-EA-15% group demonstrated acceptable DC, suitable dentin interaction, and resin tag formation.

Highlights

Introduction published maps and institutional affilDental resin composite is one of the most widely used restorative materials, exceeding166 million restorations completed in the United States (U.S.) solely [1]
It can be seen that in terms of resin tag formation, silica-filled adhesives showed similar or higher dentin penetration compared to unfilled adhesive at the dentin interface
The energy dispersive X-ray spectroscopy (EDX) analysis of adhesives belonging to various groups revealed the presence of different elements

Summary

Introduction

Introduction published maps and institutional affilDental resin composite is one of the most widely used restorative materials, exceeding166 million restorations completed in the United States (U.S.) solely [1]. The clinical success of composite restoration depends on the properties of the dental adhesive [2]. Both dentin and enamel are diverse compositionally, and bond to resin composite material using different mechanisms [3]. Various studies have demonstrated that bonding to dentin results in a weaker bond strength of the restorative material [5,6]. Numerous elements play their part to improve the bonding properties. Researchers have previously added different fillers in the adhesives to study their mechanical properties and bond iations

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