Abstract

The density, viscosity and electrical conductivity of AlCl3-amide (amide=urea, acetamide, propionamide, butyramide) ionic liquid (IL) analogues with varied molar fractions of AlCl3 were measured at temperatures ranging from 313K to 373K. All the experimental values were fitted with the empirical equations. Meanwhile, the molar volume and molar conductivity of AlCl3-amide were also obtained. Based on the results, the difference in the properties of AlCl3-amide IL analogues are mainly attributed to the species of amide ligands, which have significant effects on complex structure, ionic interaction and hydrogen bonding of IL analogues.

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