Delamination toughening assisted by phosphorus in medium-carbon low-alloy steels with ultrafine elongated grain structures

Abstract

The effect of phosphorus (P) on delamination toughening was examined for 0.4%C–1%Cr–0.7%Mn–0.2%Mo steels (mass%) comprised of ultrafine elongated grain (UFEG) structures with strong <110>//rolling direction (RD) fiber textures. The UFEG structures evolved through the plastic deformation of tempered martensitic structures by multi-pass caliber rolling at a temperature of 773K (warm tempforming, WTF). The addition of P, up to 0.093% (mass%), had little influence on the evolution of the UFEG structure and the strength of the steels. Although the tensile ductility and upper-shelf energy showed a slight tendency to decrease as the P concentration increased from 0.001% to 0.093%, the delamination perpendicular to the notch orientation of the impact specimens was pronounced over a wider temperature range. As a result of delamination, the 0.093% P-doped steel exhibited a significant inverse temperature dependence of toughness at temperatures from 250K to 350K. The delamination toughening was dominated by the UFEG structure, and further assisted by the phosphorus segregation. It was considered that the formation of distinct P segregation bands, which presented a structure consisting of brittle and ductile layers, may be especially effective in accelerating delamination and improving toughness in the P-doped steel with an UFEG structure.