Degradation on mechanical properties of virgin and recycled polylactic acid ageing in aqueous environment

Abstract

A growing demand in polylactic acid (PLA) has increased in recent years due to the increasing of non-degradable plastic wastes. The recycling of PLA waste is seen to be another permissible solution to conserve the resources. This work aims to study the degradation rate of virgin PLA (VPLA) and recycled PLA (RPLA) in terms of the mechanical properties after ageing in different aqueous environment. The samples were immersed in river water (RW) and seawater (SW) for the duration of 150 days. Tensile strength, transverse rupture strength (TRS), impact energy and hardness properties were investigated as a function of immersed time. The results revealed that the loss in the tensile strength accelerated in river water when compared to seawater. There was at least 50% of tensile strength sacrificed in recycled PLA. The TRS had dropped approximately half from its initial value after ageing in river water and about 30% after ageing in seawater. Besides, a huge decrease ranging around 70-80% from its initial impact energy was identified. However, the reduction in hardness was relatively low. The findings will help to elucidate the degradation process of PLA and the desired effect on the mechanical performance for further application.