Degradation of bisphenol A by persulfate coupled with dithionite: Optimization using response surface methodology and pathway

Abstract

The degradation efficiency of bisphenol A (BPA) was investigated in the process of persulfate (PS) coupled with dithionite (DTN) as a function of concentration of BPA, PS, DTN and solution pH. A simple response surface methodology (RSM) based on central composite design (CCD) was employed to determine the influence of individual and interaction of above variables and the optimum processing parameters. It is satisfactory of a quadratic model with low probabilities (<0.0001) at a confidence level of 95% to predict the BPA degradation efficiency. The model was well fitted to the actual data and the correlation coefficients of R2 and R2-adj were 0.9270 and 0.8885, respectively. In addition, the obtained optimum conditions for BPA degradation were 1.79 μM, 131.77 μM, 93.64 μM for BPA, PS, DTN and pH = 3.62, respectively. It achieved a degradation efficiency >90% within 150 min. Moreover, the trapping experiment of active species demonstrated that SO4·- and ·OH were the dominant species and natural water matrix showed an obvious inhibition effect on BPA degradation. The BPA degradation pathway was predicted based on GC-MS results in this study.