Abstract

Individual carbon nanotubes are filled with fullerene molecules directly on the substrate.Two different oxidation techniques for opening the tubes prior to the filling, annealing inair, and acid treatment, are compared. High-resolution transmission electron microscopyimages indicate that both methods induce defects on the sidewalls of the nanotubes. Inthe case of acid treatment, the inner walls can be damaged without affectingthe outer walls, while the inner walls are opened along with the outer ones byheating in air. The effect of acid treatment on the tubes is much stronger thanknown from bulk samples. In contrast to previous studies, we find amorphouscarbon inside the nanotubes after oxidation, and an additional high-temperatureannealing step is needed to remove these plugs in order to open the tubes for filling.

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