Deep Learning Neural Network (DNN) Coupled Laser Induced Breakdown Spectroscopy for Quantitative Analysis of Copper Alloys

Abstract

Conventional Laser Induced Breakdown Spectroscopy (LIBS) quantitative analysis, employing both calibration and calibration-free techniques, is challenged by spectral overlapping, self-absorption, and spectral broadening effects, leading to decreased accuracy. Recently, integration of machine learning (ML) algorithms with LIBS has been increasingly employed to tackle these challenges. This article explores the augmentation of LIBS with deep learning neural networks (DNN) to enhance accuracy of quantitative analysis of multi-elemental copper alloys. Sufficient training data was acquired by simulating optical emission spectra for bronze (Cu-Sn) and admiralty brass (Cu-Zn-Sn) alloys under standard laser produced plasmas conditions, encompassing different alloy concentrations, electron temperatures, and densities. We designed a regularized DNN structure, fine-tuned using a validation dataset to optimize quantitative results. The model’s accuracy was assessed with test dataset. The quantitative results demonstrated reduced loss as training spectra increased from 500 to 5000 for both alloys. The decline in mean squared error, from 2.793×10−3 to 4.283×10−5 for bronze and from 3.245×10−2 to 5.598×10−4 for admiralty brass alloys, as training data increased from 500 to 5000, underscores the proposed DNN model’s potential for metallurgical alloy quantification.