Abstract

In the present work, a new class of solvents in the name of deep eutectic solvent were prepared and used as a liquid extraction phase in a headspace single-drop microextraction method for the preconcentration of triazole fungicides from fruit juice and vegetable samples by gas chromatography. The significant parameters headspace single-drop microextraction process (the type of eutectic solvent, drop volume, stirring speed, pH and extraction temperature were optimized. Three different deep eutectic solvents, including choline chloride (as a hydrogen bond acceptor) and ethylene glycol, phenol and 4-chlorophenol (as a hydrogen bond donor) were prepared and evaluated. Choline chloride: 4-chlorophenol is the highest extraction efficiencies for the target analytes among the tested deep eutectic solvents. The limit of detections (LODs) were between 0.82 and 1.0 µgL−1 with the relative standard deviation (RSD %) ranging from 3.9 to 6.2.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.