Decomposition characteristics of natural gas hydrates in hydraulic lifting pipelines

Abstract

For the sake of guiding parameter setting of the hydraulic lifting pipeline system for cutter-suction mining of natural gas hydrates (“hydrates” for short) on the seabed, the decomposition characteristics of hydrates in hydraulic lifting pipelines and the effects of flow parameters on decomposition characteristics were studied in this paper. A temperature–pressure model for the hydrate hydraulic lifting pipeline, a hydrate decomposition mass transfer model and a pipeline multiphase flow model were established using mathematical modeling method according to thermodynamics and fluid mechanics. Then, the relationships of the temperature and pressure of pipeline fluid, the amount of hydrate particulate matter and the decomposition surface vs. the underwater depth under the effect of different influencing factors during the transformation from solid–liquid two-phase flow to solid–liquid–gas three-phase flow were analyzed. And the following research results were obtained. First, the decomposition of hydrate slows down and the decomposition surface moves upward slightly with the increase of flow rate in the pipeline. Second, particle size basically has no effects on the temperature and pressure of pipeline fluid, the hydrate phase equilibrium pressure and hydrate decomposition surface. However, only the hydrate particles whose diameter is smaller than 0.2 mm can be completely decomposed in the pipeline while the decomposition of those whose particles size is greater than 2.0 mm is negligible. Third, if the back pressure at the outlet is positive, the decomposition surface moves upward and the decomposition of hydrate slows down with the increase of the back pressure. And if the back pressure at the outlet is negative, the decomposition surface moves downward and the decomposition of hydrate speeds up with the increase of the back pressure. Fourth, the decomposition of hydrate slows down and the decomposition surface moves upward with the increase of mineral depth. However, the decomposition rate and decomposition surface are basically unchanged when the mineral depth is below 1500 m under water. Fifth, the experimental results are basically consistent with the numerical simulation results, and it is indicated that the newly established models are of high reliability. In conclusion, decomposition surface height and decomposition rate can be adjusted by controlling flow rate and outlet back pressure rationally during the cutter-suction mining of hydrates while the influences of particle diameter and mining depth on gas production need not be taken into consideration.