Decolorization of Crystal Violet from Aqueous Solution Using Electrofenton Process

Abstract

In recent years, advance oxidation processes (AOPs) have been widely interested for treatment of industrial wastewater and organic matter. At among, Electrofenton has been proposed as a strong oxidative method. So, the aim of this work was purification of colored aqueous containing crystal violet by electrofenton process and steel mesh electrodes. All regents and methods were prepared from analytical grad and standard methods. The amounts of crystal violet were determined by colorimetric using a spectrophotometer at a maximum wavelength about 586 nm. The main parameters such as pH, applied current, dye concentration, reaction time and supporting electrolyte dose were investigated. Experimental data analysis was also performed using excel software. The results of this study showed that the better dye degradation is occurred in acidic pH (pH3), contact time of 5 minutes, initial concentration of crystal violet 50 mg/l, applied current 0.8 A and an electrolyte level about 0.1 g/L of NaCl. Higher electrical current and lower pHs were caused to generate the higher amount of oxidative radical and regeneration of Fe2+. Under optimal condition, crystal violet was removed around 99.72%. Referring to the results, it can be concluded that the electrofenton is a suitable in situ hydrogen peroxide generation technology for treatment of colored wastewater.