Abstract

Agriculture can benefit from urea fertilizer because it contains a lot of nitrogen at a reasonable cost. Urea fertilizer can be stored easily and does not pose a fire hazard over time. Due to its acidifying properties, urea fertilizer is an ideal fertilizer for many plants. Input and feed of the urea unit are taken from the output of the ammonia unit (CO2 and NH3). Hence, in this study, two methods of CO2 recovery from combustion gases and CO2 recycling in ammonia units will be used to increase urea production to realize low-carbon and industrial systems (including green agriculture). CO2 recovery also reduces environmental pollution, which is a very important factor in sustainable cities and societies. The results showed that CO reduction increases the overall efficiency compared to the data reported in the world for the same process, which is due to the reduction of CO input to methanize. Collecting information around the globe for constructing the same green system considering various conditions in each environment makes complicated situations in terms of how to design the process and the observed outcomes. However, we could find a new smart design to build the green system in our case study where it is completely acceptable compared to the same systems’ outputs. The obtained results indicate that the temperature of the shift reactor can be brought closer to 365°C without reducing the selectivity of the catalysts, which in turn would increase the CO conversion rate, the CO2 output, and the overall efficiency of the unit. Finally, it is shown that the rate of CO escape from shift reactors is decreased.

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