The cleanup of CO in hydrogen for PEMFC applications using Pt, Ru, Co, and Fe in PROX reaction

Abstract

An experimental investigation is performed into the cleanup of CO in hydrogen for proton exchange membrane fuel cell (PEMFC) using Pt/Al 2O 3 and Ru/Al 2O 3 catalysts. Additionally, the effects of adding the transition metals Co and Fe to a Ru/Al 2O 3 catalyst are examined. The results show that as the level of Pt addition is increased, the maximum CO conversion rate is achieved at a lower temperature. With Ru/Al 2O 3 catalysts, the CO conversion rate increases significantly with increasing Ru addition at temperatures lower than 80 °C For both catalysts, the methane yield increases with increasing temperature and increasing noble metal addition. At temperatures in the range of 100–140 °C, the CO conversion rate and methane yield of the Pt- and Ru-based preferential oxidation (PROX) reactions are both insensitive to the density of the honeycomb carrier. The CO conversion rate is significantly improved by the addition of Fe at temperatures lower than 160 °C and by the addition of Co at temperatures higher than 200 °C. Of the two metals, Fe results in a greater reduction of the methane yield at high temperatures. Finally, both catalysts achieve a stable cleanup performance over the course of a 12-h stability test and suppress the CO concentration to an acceptable level for PEMFC applications.