Abstract
Abstract In an earlier work we have theoretically derived and explained certain rules relating the ν1/v3 frequency ratio of tetrahedral oxoanions of the transition metals with some basic properties of the anions. It is now demonstrated that these rules are also valid for oxoanions of the main group elements of the periodic system. Applying these and other relations it was possible to predict the value of the symmetric stretching frequency ν1(A1) of xenon tetroxide. Some vibrational properties of XeO4 (force constants, mean amplitudes of vibration, the Coriolis coupling constant and the bond order) are also calculated and compared with those of related species.
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