Abstract
Perfluoroalkylsilver(I) compounds are obtained via ligand exchange reactions of AgNO 3 and Cd(R f) 2 compounds in aprotic polar solvents. Equilibria between the neutral species AgR f · D and the ionic species [Ag(R f) 2] − involve silver(1) ions and exhibit strange solvent-dependency. The 19F- and 109Ag-NMR data as well as the T t-values have been measured. Reactions with e.g. C 6H 5HgCl proceed at −30°C within a few minutes to give the corresponding phenyl(perfluoroalkyl)mercury derivatives. However, the versatility of AgR f reagents as perfluoroalkyl-group transfer reagents in DMF and N(C 2H 5) 3 remains limited.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
