Abstract
AbstractA synthetic route leading to bis‐heteroleptic cyclometalated complexes magnified image is described. The complexes [2‐(2′‐thienyl)pyridinato‐N, C‐3′]{2‐[3′‐(trimethylsilyl)2′‐thienyl]pyridinato‐N, C3′}platinum(II) ([Pt(thpy) (TMS‐thpy)]; I) and (l‐phenylpyrazolato‐N2, C2′)[2‐(2′‐thienyl)pyridinato‐N, C3′]platinum ([Pt(Phpz)(thpy)]; II) are characterized by UV/VIS, NMR, and mass spectroscopy. Thermal and photochemical oxidative addition reactions yield two out of the 10 possible pairs of enantiomers of octahedral Pt(IV) compounds.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.