Abstract
Abstract2,6‐Diphenylpyridine forms, as twofold‐deprotonated, terdentate ligand, complexes with Pt(II) and Pd(II), having two adjacent five‐membered metallocycles. As mono‐deprotonated, bidentate ligand, it forms cis‐bis‐complexes having a chirality axis. Pt(II) complexes undergo thermal and photochemical oxidative addition reactions, yielding stable Pt(IV) compounds. Pd(II) complexes yield substitued 2,6‐diphenylpyridine in photochemical reactions.
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