Abstract
Catalytic activity of V, Mn, Ni, Cu, Zn, Mo, Zr and Ce oxides over an α-alumina support was evaluated for cyclohexane oxidation under oxygen deficient conditions in order to understand the relation between carbon deposition and catalytic activity/selectivity. Carbon formation over the catalysts during the oxidation reaction was measured by means of Fourier transformed infrared spectroscopy (FTIR). Catalysts Mn/Al 2O 3 and Ce/Al 2O 3, which are selective for deep oxidation of cyclohexane, possessed relatively carbon free surfaces. The catalysts with relatively high carbon deposition (V, Ni, Cu, Zn, Mo and Zr) produced CO in addition to CO 2. Traces of formaldehyde were produced over the catalysts Mo and V.
Published Version
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