Abstract

The electrochemical behaviour of phenyl-substituted ehtylenes was studied in dimethyl-formamide (DMF) and hexamethylphosphoricacid-triamide (HMPA) by cyclic voltammetry. Tetrapheyl-triphenyl-ethylene and α-methyl-stilbene showed different mechanisms in these two solvents due to a rapid disproportionation step at the anion radical stage in DMF. The different mechanisms are discussed and compared with data available from the literature.

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