Capacitive deionization and electrochemical performance of a hierarchical porous electrodes enabled by nitrogen and phosphorus doped CNTs and removable NaCl template

Abstract

Capacitive Deionization (CDI) is an electrochemical desalination technique based on the electrical double layer, which accumulate salts from the water stream; however, achieving higher salt adsorption for low-concentration salt is hindered due to several obstacles, such as low adsorption capacity and slow kinetics on the electrode surface. In this study, we reported a novel electrode fabrication method designed to enhance the hydrophilicity of the electrode material and activate hierarchical porosity, making a more accessible adsorption surface area. This modification enables more than 210 % improvement in salt adsorption capacity, achieving 17.5 mg g-1 in a single pass process with good stability in an 850 mg/L NaCl solution at 1.2 V, surpassing most reported carbon-based electrodes under similar operating conditions. Electrode formulation consists of Nitrogen (N) and Phosphorus (P) doped hierarchical carbon nanotubes (CNTs) network blended with additional NaCl as a green and removable template to reach higher levels of porosity. The electrochemical sorption behavior of the sample was characterized over a voltage range of –0.5 to 0.7 V. Furthermore, the electrode materials were characterized utilizing various characterization methods, including Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), X-ray Diffraction (XRD), Raman Spectroscopy, Fourier Transformed Infrared (FTIR), X-ray Photoelectron Spectroscopy (XPS), and Brunauer-Emmett-Teller (BET) to explore the correlation between microstructure, morphology, and properties. Our finding reveals that not only N and P can affect adsorption, but also the novel cathode preparation method, which employs a removable NaCl templated hierarchical porous electrode, has a profound effect on the electrochemical and CDI results. This finding will open a new perspective in designing electrodes for all electrochemical systems.