Abstract

The DOE Office of Fossil Energy Solid Oxide Fuel Cell (SOFC) Program is interested in the near-term commercialization of high-temperature SOFC and solid oxide electrolyzer cell (SOEC) technologies that are robust, reliable, and resilient. A recent report delivered to the United States Congress highlighted several development recommendations including the design of pilot-scale units, continued early stage research and development, increased industrial engagement, and the exploration of reversible operation of SOFC technology.The National Energy Technology Laboratory (NETL) SOFC research group currently addresses most of these recommendations. NETL’s in-house research efforts focus on the characterization, simulation, and mitigation of high temperature degradation of fuel cell components. The capstone of these efforts is NETL’s SOFC degradation modeling framework, which uses NETL supercomputing facilities to simulate SOFC performance degradation of thousands of possible electrode configurations experiencing multiple simultaneous degradation modes under a broad array of relevant operating conditions. The models for the different degradation modes are based upon experimental data (1) generated in-house, (2) referenced from available scientific publications, and (3) shared from collaborations with other industrial, academic, and national laboratory partners within the SOFC Program. The team then employs techniques in data analytics to select optimal electrodes to maximize the SOFC performance for given operating conditions. These modeling efforts guide electrode engineering efforts in-house and through external collaborations by identifying (1) which degradation modes contribute the most to overall performance degradation for given operating conditions and (2) which electrode features will have the greatest impact on lowering cell degradation and system costs. Additionally, the development on non-invasive in situ high temperature fiber optic sensors for temperature and gas composition measurement provides valuable data for inclusion in degradation models as well as informing technology development at the commercial scale. Finally, the wealth of experience gained in development degradation models and materials for reducing the cost of SOFC technology is being readily applied to reducing the cost of SOEC technology.NETL will report on its most recent progress in the field of SOFC and SOEC development, including degradation modeling, in situ fiber optic sensor development, electrode engineering, and relevant systems-level analyses.

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