Abstract
The interaction of tris(6-methyl-2-pyridyl)phosphine oxide (L) with equimolar amounts of [Cu(MeCN)4]PF6 or AgClO4 in acetonitrile produces scorpionate-like complexes [M(L)(MeCN)]X (M = Cu and Ag; X = PF6- and ClO4-). At ambient temperature, these compounds exhibit orange (λmax = 608 nm) or turquoise (λmax = 490 nm) photo-luminescence with a quantum yield up to 16% and lifetimes of microsecond order.
Published Version
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