Abstract
Novel Cu@Fe3O4 core-shell nanoparticles prepared via a simple reduction method were evaluated for degradation of oxytetracycline (OTC) in pre-treated leachate (Lp-TREA) (leachate treated by conventional methods). Changes in the characteristics of dissolved organic matter (DOM) in the leachate were also investigated to gain a better understanding of the effects of DOM on the performance of Cu@Fe3O4. An excellent OTC degradation of >99% was achieved within 30 min under conditions of 1 g/L Cu@Fe3O4, 20 mg/L OTC, 20 mM H2O2, and initial pH 3.0, which was similar to the efficiency obtained in deionized water (90% even at pH 9.05). Humic acid (HA) and fulvic acid (FA) were completely degraded at initial pH 3, while aromatic protein (AP) with 32.7% of 1–3 kDa constituents were totally transformed to 0.5–1 kDa compounds, and 17% < 0.5 kDa material was degraded. The OTC removal rate decreased gradually as Cu@Fe3O4 was repeatedly used, but it was significantly enhanced when Cu@Fe3O4 was washed after five uses to remove the organic matter on its surface. The results suggest that Cu@Fe3O4 is a promising and effective catalyst for pharmaceutical and personal care product degradation in landfill leachates.
Published Version
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