Abstract

The development of Cu-catalyzed coupling of vinylidene cyclopropanes with allyl or allenyl boronates is reported. The reaction forms a C-C bond at the terminal carbon atom of the allene moiety of vinylidene cyclopropanes with concurrent opening of the cyclopropane ring. In addition, the resulting Cu-enolate intermediate can be intercepted by external electrophiles.

Full Text
Published version (Free)

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call