Abstract

Accurate values of ET + electron-molecular vibration ( e-mv) coupling contants have been obtained through polarized microreflectance spectra of (ET) 2[Mo 6O 19], The information gained allow us to fully analyze the spectra of a different CT complex, (ET) 2[Pt(S 2C 4O 2) 2]where ET + dimers are separated by the Pt(II)-dithiosquarate ion. In this case, a partial CT is observed between ET dimers and the anion.

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